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Journals and Conferences
A series of 9,10-diarylphenanthrenes was prepared, and their structures and dynamic behaviors were both theoretically and experimentally investigated. A more twisted and crowded phenanthrene backbone was associated with a lower barrier to the rotation of an aryl group.
The syntheses, structures, and physical properties of a full series of benzannulated tetraphenylenes are reported. The palladium-catalyzed annulation of tetraiodo-substituted 2,3,6,7,10,11,14,15-octamethyltetraphenylene with insufficient di(4-anisyl)ethyne yielded a mixture of per-substituted circulene and its non-planar fragments, including mono-,… (More)
Zethrene-based condensed arenes dinaphthozethrene and diindenozethrene were synthesized by oxidative cyclodehydrogenation and palladium-catalyzed cyclization of 7,14-diarylzethrenes, respectively. Their structures were analyzed by X-ray crystallography. The photophysical and electrochemical properties of these compounds were investigated.
The palladium-catalyzed annulation of 9-bromo- and 9-chlorophenanthrenes with alkynes gave 4,5-disubstituted acephenanthrylenes in yields of 58-95% (9 examples). Asymmetric alkynes, such as 1-phenyl-1-propyne, 1-phenyl-1-hexyne, and 1-cyclopropyl-2-phenylethyne, regioselectively form (cyclo)alkyl-substituted products, following the regular rule that governs… (More)