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The thio-amide and quaternary amine parts of the title compound, C(6)H(15)N(2)S(+)·Cl(-), are mutually almost perpendicular, the dihedral angle being 80.6 (7)°. The thio-amide group is planar and adopts a Z conformation, whereas the amine end of the cation is in an extended conformation. In the supra-molecular structure, mol-ecules are linked into… (More)