James Thuman

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Model compounds that structurally mimic the hydrogen-producing active site of [FeFe]-hydrogenases have been studied to explore potential ground-state electronic structure effects on reaction mechanisms compared to hexacarbonyl derivatives. The time-dependent behavior of Fe2(μ-S2C3H6)(CO)4(PMe)2 (A) in room temperature n-heptane and acetonitrile solutions(More)
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