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The role of a phosphatidylcholine-specific phospholipase C in the production of diacylglycerol for nitric oxide synthesis in macrophages activated by IFN-gamma and LPS.
Through analysis of diacylglycerol (DAG) synthesis and choline metabolism in activated macrophages, direct evidence is provided that NO synthesis involves the activation of an unusual phosph atidylcholine-specific phospholipase C (PC-PLC) and not a phosphatidylinositol-specificospholipases C (PI-P LC) or phospholIPase D (PLD).
Nitrogen, oxygen and sulfur ylide chemistry : a practical approach in chemistry
- J. S. Clark
1. Nitrogen, oxygen and sulfur ylides: an overview 2. Ammonium, Oxonium and Sulfonium Ylides 3. Azomethine, Carbonyl and Thiocarbonyl Ylides 4. Nitrile Ylides
Synthesis of medium ring ethers. Part 2. Synthesis of the fully saturated carbon skeleton of Laurencia non-terpenoid ether metabolites containing seven-, eight- and nine-membered rings
A general method for the construction of medium ring ethers is described in which a 2-substituted cycloalkanone was subjected to a Baeyer–Villiger ring expansion to the lactone, Tebbe methylenation…
Diastereoselective anti Aldol Reactions of Chiral Ethyl Ketones. Enantioselective Processes for the Synthesis of Polypropionate Natural Products.
Stereoselective Synthesis of the Cyclic Ether Core of (+)-Laurenyne.
Synthesis of Medium Ring Ethers. Part 5. The Synthesis of (+)‐ Laurencin
Trialkylphosphine-Mediated Synthesis of 2-Acyl Furans from Ynenones.
- Chao‐Fan Xu, Stéphane Wittmann, M. Gemander, Venla Ruohonen, J. S. Clark
- Chemistry, MedicineOrganic letters
- 27 June 2017
A novel reaction for the synthesis of 2-acyl furans is reported, which offers efficient access to biologically important compounds, including fused polycyclic compounds and furaldehydes, from simple starting materials.
New procedure for the direct generation of titanium enolates. Diastereoselective bond constructions with representative electrophiles
Les enolates de titane sont prepares a partir des precurseurs carbonyles correspondants avec TiCl 4 et une amine tertiaire, dans des conditions douces
Diastereoselective aldol reactions using .beta.-keto imide derived enolates. A versatile approach to the assemblage of polypropionate systems
is the pyramidality of the nitrogens?O clearly disposing the methyl groups to axial and equatorial positions. We assume the nitrogens are more nearly trigonal in 2 by analogy to most…