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Hydrogen storage in metal-organic frameworks.
TLDR
This critical review of the current status of hydrogen storage within microporous metal-organic frameworks provides an overview of the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity. Expand
Carbon dioxide capture in metal-organic frameworks.
Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long
Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
Two representative metal–organic frameworks, Zn4O(BTB)2 (BTB3− = 1,3,5-benzenetribenzoate; MOF-177) and Mg2(dobdc) (dobdc4− = 1,4-dioxido-2,5-benzenedicarboxylate; Mg-MOF-74, CPO-27-Mg), areExpand
Introduction to metal-organic frameworks.
Exploiting single-ion anisotropy in the design of f-element single-molecule magnets
Scientists have long employed lanthanide elements in the design of materials with extraordinary magnetic properties, including the strongest magnets known, SmCo5 and Nd2Fe14B. The properties of theseExpand
Carbon dioxide capture: prospects for new materials.
TLDR
The most recent developments and emerging concepts in CO(2) separations by solvent absorption, chemical and physical adsorption, and membranes, amongst others, will be discussed, with particular attention on progress in the burgeoning field of metal-organic frameworks. Expand
Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5).
TLDR
The air-free compound exhibits the highest gravimetric and volumetric H2 uptake capacities yet demonstrated for a cryogenic hydrogen storage material and no loss of capacity was apparent during 24 complete adsorption−desorpti... Expand
Kondo resonance in a single-molecule transistor
TLDR
The Kondo resonance can be tuned reversibly using the gate voltage to alter the charge and spin state of the molecule and persists at temperatures up to 30 K and when the energy separation between the molecular state and the Fermi level of the metal exceeds 100 meV. Expand
Evaluating metal–organic frameworks for natural gas storage
Metal–organic frameworks have received significant attention as a new class of adsorbents for natural gas storage; however, inconsistencies in reporting high-pressure adsorption data and a lack ofExpand
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