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- Publications
- Influence
A Stable Aminyl Radical Metal Complex
- T. Büttner, J. Geier, +5 authors H. Grützmacher
- Chemistry, Medicine
- Science
- 14 January 2005
Metal-stabilized phenoxyl radicals appear to be important intermediates in a variety of enzymatic oxidations. We report that transition metal coordination also supports an aminyl radical, resulting… Expand
Epikutantestung mit chemisch modifiziertem Kolophonium
Anmerkung * Teil 1: Geier J, Hausen BM: Epikutantestung mit chemisch modifiziertem Kolophonium. Ergebnisse einer Studie der Deutschen Kontaktallergie−Gruppe (DKG) und des Informationsverbundes… Expand
Synthese und Struktur von Natriumoligophosphandiiden im System PhPCl2/Na
- J. Geier, H. Rueegger, M. Wörle, H. Grützmacher
- Chemistry
- 25 August 2003
Stereochemische Kontrolle des Redoxpotentials von tetrakoordinierten Rhodium-Komplexen†
- Cécile Laporte, F. Breher, J. Geier, J. Harmer, A. Schweiger, H. Grützmacher
- Chemistry
- 3 May 2004
Electron paramagnetic resonance spectrum of the FCO2 radical isolated in noble gas matrices.
- H. Beckers, H. Willner, D. Grote, W. Sander, J. Geier
- Chemistry, Medicine
- The Journal of chemical physics
- 10 June 2008
The EPR spectra of the fluoroformyloxyl radical FCO(2) isolated in noble gas matrices at temperatures from 5 to 30 K have been investigated. This study provides principal g values and (19)F hyperfine… Expand
Formation of hexacarbonylmanganese(I) salts, [Mn(CO)6]+X-, in anhydrous HF.
- J. Geier, H. Willner, C. Lehmann, F. Aubke
- Chemistry, Medicine
- Inorganic chemistry
- 7 July 2007
A convenient one-step synthesis for [Mn(CO)6]+ salts has been developed. The method involves the one-electron oxidation of Mn2(CO)10 by protons in solutions of Lewis acids (BF3, (CF3)3BCO) and… Expand
Spatial shape of electron delocalization: structure of the laplacian of the negative exchange-correlation density.
- J. Geier
- Chemistry, Medicine
- The journal of physical chemistry. A
- 6 July 2006
The Laplacian of the negative exchange-correlation density (with respect to coordinate r(2)), nabla<(r)2>(2)[-Gamma(sigma1)(sigma2)(XC) (r(1),r(2))] = nabla(r)2(2)X(sigma1)(sigma2)(r(1),r(2)), is… Expand
Cesium hydridotris(trifluoromethyl)borate, Cs[(CF3)3BH].
- J. Geier, G. Pawelke, H. Willner
- Chemistry, Medicine
- Inorganic chemistry
- 7 August 2006
Treatment of Cs[(CF3)3BNH2] with the aminating agent H2NOSO3H in aqueous solution allowed the isolation of pure Cs[(CF3)3BH], which is stable up to 300 degrees C. Due to the strong… Expand