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Planar chips technology for miniaturization and integration of separation techniques into monitoring systems. Capillary electrophoresis on a chip
Miniaturization of already existing techniques in on-line analytical chemistry is an alternative to compound-selective chemical sensors. Theory on separation science predicts higher efficiency,Expand
Thermodynamic, spectroscopic, and computational evidence for the irreversible conversion of β- to α-endosulfan
Previous studies have provided unequivocal evidence for the symmetry of beta-endosulfan and the corresponding asymmetry of alpha-endosulfan; the conversion of beta-endosulfan to alpha-endosulfan wasExpand
Nematode-Antagonistic Trichothecenes from Fusarium equiseti
A strain of the fungus Fusarium equiseti isolated from soybean cyst nematode secretes nematode-antagonistic compounds. Bioassay-guided fractionation of an extract of the culture broth was undertakenExpand
Four psychrotolerant species with high chemical diversity consistently producing cycloaspeptide A, Penicillium jamesonlandense sp. nov., Penicillium ribium sp. nov., Penicillium soppii and
Penicillium jamesonlandense is a novel species from Greenland that grows exceptionally slowly at 25 degrees C and has an optimum temperature for growth of 17-18 degrees C. The novel species is moreExpand
Silyl fluoride electrophiles for the enantioselective synthesis of silylated pyrrolidine catalysts.
Chiral silylated pyrrolidine catalysts are obtained in high yield and enantioselectivity by sparteine-mediated lithiation of N-Boc-pyrrolidine and addition to silyl fluoride electrophiles. TheExpand
Hydrotris(pyrazolyl)borate molybdenum chemistry: spin triplet 16-electron carbonyl derivatives of molybdenum (II), and the X-ray structure of the Mo(V) oxo compound {HB(3,5-Me2C3N2H)3} MoOI2
Abstract The hydrotris(3,5-dimethylpyrazolyl)borate complexes Tp ∗ Mo ( CO ) 2 X ( X = Cl, I ) are rare examples of 16-electron carbonyl derivatives with a spin triplet ground state, which exhibitExpand
Facile activation of dihydrogen by an unsaturated heavier main group compound.
The germanium alkyne analogue Ar'GeGeAr' (1, Ar' = C6H3-2,6(C6H3-2,6-Pri2)2) reacts with 1, 2, or 3 equiv of dihydrogen at room temperature, and at 1 atm pressure, to afford a mixture of the productsExpand
Micromachining of monocrystalline silicon and glass for chemical analysis systems A look into next century's technology or just a fashionable craze?
Miniaturization of already existing techniques in on-line analytical chemistry is an alternative to compound-selective chemical sensors. Theory indicates higher efficiency, faster analysis time andExpand
Ion channel formation from a calix[4]arene amide that binds HCl.
The ion transport activity of calix[4]arene tetrabutylamide 1,3-alt 2 was studied in liposomes, planar lipid bilayers, and HEK-293 cells. These experiments, when considered together with (1)H NMR andExpand
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