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Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV – gas phase reactions of organic halogen species
This article, the fourth in the series, presents kinetic and photochemical data sheets evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gasExpand
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reaxtions of Ox, HOx, NOx and SOx species
This article, the first in the series, presents kinetic and photochemical data evaluated by the IUPAC Subcommit- tee on Gas Kinetic Data Evaluation for Atmospheric Chem- istry. It covers the gasExpand
Atmospheric oxidation capacity sustained by a tropical forest
TLDR
It is proposed that natural VOC oxidation, notably of isoprene, recycles OH efficiently in low-NOx air through reactions of organic peroxy radicals, which demonstrates that the biosphere maintains a remarkable balance with the atmospheric environment. Expand
Carbon 13 and D kinetic isotope effects in the reactions of CH4 with O(1 D) and OH: New laboratory measurements and their implications for the isotopic composition of stratospheric methane
Measurements of the 13C and D kinetic isotope effects (KIE) in methane, 13CKIE = k(12CH4)/k(13CH4) and DKIE = k(12CH4)/k(12CH3D), in the reactions of these atmospherically important methaneExpand
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III - gas phase reactions of inorganic halogens
This article, the third in the series, presents ki- netic and photochemical data evaluated by the IUPAC Sub- committee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gasExpand
Activation of Br2 and BrCl via uptake of HOBr onto aqueous salt solutions
The reactive uptake of HOBr onto aqueous solutions containing Cl− and Br− has been studied using a wetted-wall flow tube reactor. The uptake was found to be limited by gas phase transport, enablingExpand
The Comparative Reactivity Method ? a new tool to measure total OH Reactivity in ambient air
Hydroxyl (OH) radicals play a vital role in main- taining the oxidizing capacity of the atmosphere. To under- stand variations in OH radicals both source and sink terms must be understood. CurrentlyExpand
The heterogeneous reactivity of gaseous nitric acid on authentic mineral dust samples, and on individual mineral and clay mineral components
The heterogeneous reaction between HNO3 and various authentic dust, mineral and clay mineral surfaces has been investigated by means of the Knudsen reactor technique at ≈296 K. Authentic dustExpand
Direct detection of OH formation in the reactions of HO 2 with CH 3 C(O)O 2 and other substituted peroxy radicals
This work details the first direct observation of OH as a product from (R1): HO 2 +CH 3 C(O)O 2 →(products), which has generally been considered an atmospheric radical termination process. TheExpand
Ozone decomposition on Saharan dust: an experimental investigation
Abstract. The heterogeneous reaction between O 3 and authentic Saharan dust surfaces was investigated in a Knudsen reactor at approx 296 K. O 3 was destroyed on the dust surface and O 2 was formedExpand
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