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Quantification of F-ring isoprostane-like compounds (F4-neuroprostanes) derived from docosahexaenoic acid in vivo in humans by a stable isotope dilution mass spectrometric assay.
- E. Musiek, J. Cha, +5 authors J. Morrow
- Chemistry, Medicine
- Journal of chromatography. B, Analytical…
- 5 January 2004
Lipid peroxidation has been implicated in the pathophysiological sequelae of human neurodegenerative disorders. It is recognized that quantification of lipid peroxidation is best assessed in vivo by… Expand
Acyclic Stereocontrol Induced by Allylic Alkoxy Groups. Synthetic Applications of Stereoselective Dihydroxylation in Natural Product Synthesis
An enantioselective synthesis of (−)-slaframine
Abstract An enantioselective synthesis of (−)-slaframine ( 1 ) has been accomplished by an intramolecular azide [2+3] dipolar cycloaddition starting from the readily available aldehyde 12 .
HIGHLY STEREOSELECTIVE APPROACHES TO α- AND β-C-GLYCOPYRANOSIDES
Nucleophilic attack on 4,6-dimethoxy-2-pyrones; discovery of a remarkably facile rearrangement of the pyrones
Abstract During the course of mechanistic investigations of nucleophilic attach on 4,6-dimethoxy-2-pyrones, a rapid scrambling reaction has been found between 4,6-dimethoxy-3-methyl-2-pyrone and the… Expand
The Scope and Mechanism of Rearrangement of 4,6-Dialkoxy-2-pyrones.
Total Synthesis of Clavepictines A and B. Diastereoselective Cyclization of δ-Aminoallenes.
Highly stereoselective approaches to .alpha.- and .beta.-C-glycopyranosides
Stereochemistry of palytoxin. 4. Complete structure