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Structural characterization of five-coordinate copper(II), nickel(II), and cobalt(II) thiocyanato complexes derived from bis(2-(3,5-dimethyl-1-pyrazolyl)ethyl)amine
The reaction of M(ClO 4 ) 2 ·6H 2 O with NH 4 NCS in presence of the organic sterically hindered bis(2-(di-3,5-dimethyl-1-pyrazolyl)ethyl)amine (bedmpza) afforded the five-coordinate mononuclearExpand
The rate earth transition metal phosphide oxides LnFePO, LnRuPO and LnCoPO with ZrCuSiAs type structure
Abstract The compounds LnFePO (Ln = La−Nd, Sm, Gd), LnRuPO (Ln = La−Nd, Sm, Gd) and (Ln = La−Nd, Sm) crystallize with the tetragonal) ZrCuSiAs type structure (P4/nmm, Z = 2), which was refined fromExpand
DNA Cleavage by Structurally Characterized Dinuclear Copper(II) Complexes Based on Triazine
The reaction of 2-chloro-4,6-bis(di-2-picolylamino)-1,3,5-triazine (bdpaT Cl ) with copper(II) perchlorate and copper(II) chloride afforded two dinuclear complexes [Cu2(μ-bdpaT ClExpand
Towards the chemical control of molecular packing: syntheses and crystal structures of three trans-[NiL4(NCS)2] complexes.
A study of the molecular Hirshfeld surfaces, together with density functional theory (DFT) calculations, provide insights into the origin of the Molecular packing features, and it is suggested that the greater crystal density of (III) results from smaller intermolecular electrostatic repulsions. Expand
Polynuclear croconato-bridged-copper(II) complexes derived from tri- and tetra-dentate amines
Abstract Three new polynuclear bridged croconato copper(II) complexes with different dimensionality {[Cu(bedmpza)(μ2-C5O5)]·4H2O}n (1), {[Cu3(aepn)3(μ2-C5O5)(μ3-C5O5)(H2O)](ClO4)2·1.6H2O}n (2), andExpand
On the order and disorder of the transition metal (T) and silicon atoms in ternary thorium transition metal silicides of the compositions Th2TSi3 and ThTSi
Abstract During phase investigations of the ternary systems thorium-transition metal-silicon, 12 ternary thorium transition metal silicides Th2TSi3 (T = Mn, Fe, Co, Ni, Cu, Ru, Rh, Pd, Os, Ir, Pt,Expand
Synthesis, structural and biological studies of two new Co(III) complexes with tridentate hydrazone ligand derived from the antihypertensive drug hydralazine
Abstract A new Schiff base derived from the antihypertensive hydralazine (LH) and its Co(III) complexes [CoL2]X*4H2O, where X = NO3− (1) or Cl− (2), were synthesized and characterized using FTIR,Expand
Pyridine as trigger for chloride isomerisation in chelated ruthenium benzylidene complexes: implications for olefin metathesis.
The cationic pyridine adduct of a ruthenium complex bearing a chelating benzylidene and an N-heterocyclic carbene was identified as an intermediate during the activation of cis dichloro species and aExpand
XRD evidence for the electrochemical formation of Li+(PC)yCn- in PC-based electrolytes
The reduction of graphite in propylene carbonate (PC) based electrolytes is a complex process involving solvated lithium–graphite intercalation compounds (GICs), Li+(PC)yCn-. XRD performed in situ toExpand