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Tumor necrosis factor α is an inflammatory cytokine which has been linked with many infectious and inflammatory diseases. Detection and quantification of this key biomarker is commonly achieved by… (More)
The role of agostic bonds in chemistry is highlighted. In particular, attention is given to the origin of the term, methods of investigations and their function in chemistry.
In this work a DFT study of the structure−function−performance relationship of bis(cyclopentadienyl)-based (Cp2-based) group 4 metallocenes is presented. In particular, the effects of (1) the metal,… (More)
The plateau modulus \( G_N^0 \) is an important material parameter reflecting structural aspects of molecular interaction in polymers such as entanglement molecular weight Me. We determine these… (More)
The collagen protein provides tensile strength to the extracellular matrix in addition to localising cells, proteins and protein cofactors. Collagen is susceptible to a build up of glycation… (More)
In this paper we communicate mechanistic investigations of the asymmetric catalytic hydrosilylation of imines using (R,R)-ethylene-1,2-bis(η5-4,5,6,7-tetrahydro-1-indenyl)titanium… (More)
Abstract Propene oligomerisation was successfully performed at a temperature range from −20 °C to + 70 °C with the precursor [Cp(C5H4SiMe2tol)ZrMe2] (Cp = C5H5; tol = p-C6H5Me) and either B(C6F5)3 or… (More)