Ioana Barbul

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The structure of the title compound, [Sn(2)Br(1.97)Cl(4.03)(OH)(2)(H(2)O)(2)]·2C(3)H(6)O, contains two hexa-coordinated Sn atoms bridged symmetrically by two hydroxide groups, with an inversion center in the middle of the planar Sn(2)O(2) ring, half of the mol-ecule being generated by inversion symmetry. The other sites of the distorted octa-hedral(More)
The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn⋯Cl [3.691 (2) Å] inter-actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta-coordinated and have a distorted octa-hedral Ψ-SnCl(3)O(2) coordination geometry. The O(More)
Hydrolysis of [2-{(CH2O)2CH}C6H4]2SnCl2 (1) [prepared from 2-[(CH2O)2CH]C6H4MgBr and SnCl4, in 2 : 1 molar ratio] gave [2-(O=CH)C6H4]2SnCl2 (2). Treatment of with the appropriate amine, in the absence of a solvent or catalyst, resulted in the isolation in high yields of [2-(RN[double bond, length as m-dash]CH)C6H4]2SnCl2 [R = 2'-C10H7 (3), 2',4',6'-Me3C6H2(More)
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