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Euryjanicin A: A New Cycloheptapeptide from the Caribbean Marine Sponge Prosuberites laughlini.
Aqueous V(V)-peroxo-amino acid chemistry. Synthesis, structural and spectroscopic characterization of unusual ternary dinuclear tetraperoxo vanadium(V)-glycine complexes.
The collective physicochemical properties of the two ternary species 1 and 2 project the chemical role of the low molecular mass biosubstrate glycine in binding V(V)-diperoxo units, thereby stabilizing a dinuclear V (V)-tetraperoxo dianion.
Euryjanicin A: a new cycloheptapeptide from the Caribbean marine sponge Prosuberites laughlini.
pH-specific synthetic chemistry and solution studies in the binary system of iron(III) with the alpha-hydroxycarboxylate substrate quinic acid: potential relevance to iron chemistry in plant fluids.
Solution speciation studies of the binary system unravel the aqueous species distribution as a function of pH and reagent molar ratio, and corroborate the EPR results proposing the existence of a neutral Fe(III)-quinate complex form.
Kallolide A acetate pyrazoline
- I. Rodríguez-Escudero, Jeffrey Marrero, Abimael D Rodríguez
- ChemistryActa crystallographica. Section E, Structure…
- 7 December 2011
In the crystal structure of kallolide A acetate pyrazoline, molecules are linked by weak C—H—H⋯O interactions, forming a two-dimensional network parallel to (001), and an intramolecular C-H⊯O hydrogen bond is also present.
Assessment of the clinical utility of pharmacogenetic guidance in a comprehensive medication management service
- I. Rodríguez-Escudero, Julio A. Cedeño, J. Duconge
- MedicineJournal of the American College of Clinical…
- 1 September 2020
To the authors' knowledge, this is the first time that PGx‐driven recommendations have been incorporated into a Comprehensive Medication Management service in a Hispanic population.