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We have realized a new porous metal-organic framework UTSA-76a with pyrimidine groups on the linker, exhibiting high volumetric methane uptake of ~260 cm(3) (STP) cm(-3) at 298 K and 65 bar, and… Continue Reading
A novel zinc(II) metal-organic framework UTSA-67a with narrow one-dimensional (1D) pore channels and inner cages of moderate size has been developed for highly selective separation of C2H2/C2H4… Continue Reading
Capturing carbon dioxide (CO2) from flue gases with porous materials has been considered as a viable alternative technology to replace traditional liquid amine adsorbents. A large number of… Continue Reading
Metal-organic frameworks (MOFs) have been emerging as promising multifunctional materials and have shown particularly useful applications for gas storage and separation. We have briefly outlined the… Continue Reading
Achieving stepwise photochromism in a combined molecule to access all of the possible ring-open/closed isomers is a challenge due to facile energy transfer from ring-open dithienylethene (DTE) to an… Continue Reading
Realization of ideal molecular sieves, in which the larger gas molecules are completely blocked without sacrificing high adsorption capacities of the preferred smaller gas molecules, can… Continue Reading
A new lvt-type metal-organic framework UTSA-60a with suitable pore channels and open metal sites has been developed for highly selective separation of C2H2/C2H4 at room temperature.
A novel metal-organic framework (MOF), [Cu2L(H2O)2]·7DMF·4H2O [ZJU-40; H4L = 5,5'-(pyrazine-2,5-diyl)diisophthalic acid], with Lewis basic nitrogen sites has been constructed and structurally… Continue Reading
Eight compounds were isolated from the seeds of Holarrhena antidysenterica Wall.ex A.DC. On the basis of physico-chemical properties and spectroscopic data, holarrhenanan (1) was identified as a new… Continue Reading
Extensive research has been devoted to developing new porous materials with high methane storage capacity. While great progress has been made in recent years, it still remains very challenging to… Continue Reading