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Novel Basic Ligands for the Homogeneous Catalytic Carbonylation of Methanol, XXIII. - The Influence of (Ether-Phosphane) Ligands on Alkyl Migration in Rhodium Complexes The cationic complexes… Continue Reading
[(COD)Rh(Cl)(P1∼O)] (3) is obtained from [µ-ClRh(COD)]2 (1) and the (ether-phosphane) ligand P1∼O (2) [P1∼O = Ph2PCH2CH2OCH3]. 3 reacts with AgSbF6 to form the cationic η2-Pl͡ O rhodium complex… Continue Reading
Abstract PhP(CH2C4H7O2)2 (1) and [-CH2(Ph)P~D]2 (3a-c) [D = CH2C4H702 (a), CH2C4H7O (b). CH2CH2OCH3 (c)] are obtained by reaction of Li2PPh and Na(Ph)P~D with ClCH2C4H7O2 and C1CH2CH2Cl,… Continue Reading
[ (C 0 D )R h (C l)(P '~ 0 )] (3) is obtained from [i/-C lR h(CO D )]2 (1) and the (ether-phosphane) ligand P'—O (2) [P’—O = Ph2PCH2CH2O C H 3]. 3 reacts with AgSbF6 to form the cationic 772-P l—O… Continue Reading