Hideta Ishihara

Learn More
  • Hydrate, 2CdBr4-4H2O, +4 authors Hartmut Fuessc
  • 2000
The structure of the condensed bromocadmate anions in [C(NH2)3]Cd2Br5 (1) and [H2NNH3]3CdBr5 (2) were studied at room temperature by X-ray diffraction. (1) crystallizes with double-chains bridged by Br atoms (orthorhombic, Pmmn, Z = 2, a = 1394.0(5), b = 394.5(1), c = 1086.9(5) pm). This chain structure was not described previously. (1) shows threeBr NQR(More)
The Hg atoms in the crystal structure of the title compound, (CH(6)N(3))(2)[HgBr(4)], are tetra-hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2-) tetra-hedral ions are linked to the [C(NH(2))(3)](+) ions by bromine-hydrogen bonds, forming a three-dimensional network. In the structure, the anions are located on special positions. The two(More)
The Hg atom in the crystal structure of the title compound, (CH(6)N(3))(2)[HgI(4)], is tetra-hedrally coordinated by four I atoms. The [HgI(4)](2-) ions are inter-connected to the [C(NH(2))(3)](+) ions by N-H⋯I hydrogen bonds, forming a three-dimensional network. The four different observed Hg-I distances [2.760 (2), 2.7762 (15), 2.8098 (14) and 2.833 (2)(More)
  • 1