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This paper presents a comparative study between peracetic acid (Pa), peroxymonosulfuric acid (Ps) and hydrogen peroxide (P) as bleaching chemicals for unbleached softwood kraft pulp. The theoretical… Continue Reading
The one electron oxidation and coupled oxygen atom transfer of cis-dioxomolybdenum(VI) tetraphynylporphyrin, O2Mo(TPP), was investigated by the use of cyclic voltammetry and thin-layer… Continue Reading
Both the «H 3 [PW 12 O 40 ].yH 2 O» and the «H 2 WO 4 /H 2 O 2 -H 2 O/H 3 PO 4 » systems show several 31 P and 183 W NMR signals which may be assigned to new phosphatooxoperoxotungstate species, [PW… Continue Reading
Abstract Tertiary phosphines are oxidized by cis -dioxomolybdenum(VI) tetra p -tolyl porphyrin. The rate of reaction is mainly dependent of the steric hindrance of the phosphine. Relevance to a… Continue Reading
The title diazomalonates, when treated with copper powder in octane, yield lactones of 1-hydroxymethyl 7-carboxy cycloheptatrienes. The yields of cyclisation product from such diazoesters may be… Continue Reading