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BACKGROUND AND METHODS: A single centre study including 52 German patients aged ≥16 years with severe haemophilia A was performed to compare the amount of clotting factor and outcome between… (More)
Abstract We describe a new and inexpensive method of purifying C 60 by fractional crystallization in 1, 3-diphenylacetone. After three steps, 99.5% pure C 60 was obtained with a global yield of 69%.… (More)
Interest in therapeutic applications of carbon monoxide release to physiological targets has led us to explore a photochemical strategy for such CO delivery. Here, we describe the photoactivated… (More)
Easy does it! The chemoselective oxidative α-C(sp(3))-H alkylation/cyclization reaction of N-benzyl carbamates using simple mono-, di-, and trisubstituted olefins provides functionalized… (More)
A new class of modifiable sulfur tethers is developed for aromatic C—H functionalization reactions.
This method uses a TEMPO oxoammonium salt (TBF) as a mild and nontoxic oxidant with readily available iron salts as catalysts for the synthesis of the title compounds.
This methodology provides a safe and easy way to prepare α-functionalized ethers and amines using oxoammonium TEMPO salt as easy-to-handle nontoxic oxidant.
The cross dehydrogenative coupling (CDC) of cyclic benzyl ethers with aliphatic and α,β-unsaturated aldehydes has been developed. The mild reaction conditions, in which an N-oxoammonium salt derived… (More)