In the mol-ecular structure of the title compound, [NiCl2(C7H12N2S)2], the Ni(II) atom has a distorted tetra-hedral geometry, coordinated by two Cl atoms [Ni-Cl= 2.2336 (6) Å] and two thione S atoms… (More)
The mol-ecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the Cu(II) atom with a distorted tetra-hedral geometry from two Cl atoms [Cu-Cl = 2.2182 (6) Å] and two thione S atoms [Cu-S… (More)
The mol-ecular structure of the title compound, [ZnCl2(C11H20N2S)2], shows tetra-hedral Zn coordination from two Cl ligands and two thione groups. The Zn-Cl bond lengths differ sligthly at 2.2310… (More)
In the structure of the title compound, [Pd(C(19)H(21)N(2)P)(2)](PF(6))(2)·2.85CH(3)CN, the two six-membered NHC-phosphane chelate rings form a distorted square-planar coordination geometry around… (More)
The mol-ecular structure of the title compound, [CuCl(C7H12N2S)2], shows a slightly distorted trigonal-planar coordination geometry of the Cu atom. The Cu-Cl bond measures 2.2287 (9) Å, and the two… (More)
The mol-ecular structure of the title compound, [Ni(C(19)H(21)N(2)P)(2)]I(2)·2CH(3)CN, shows two six-membered N-heterocyclic carbene/phosphane chelate rings that form a nearly square-planar… (More)
Highly efficient, one-step synthesis of sulfur-containing heteroacenes was achieved through palladium-catalyzed C-S cross-coupling of bis-alkynes with thioacetate as hydrogen sulfide surrogate.… (More)