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Uniaxial negative thermal expansion and metallophilicity in Cu3[Co(CN)6]
Abstract We report the synthesis and structural characterisation of the molecular framework copper(I) hexacyanocobaltate(III), Cu3[Co(CN)6], which we find to be isostructural to H3[Co(CN)6] and theExpand
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Recipes for improper ferroelectricity in hybrid perovskites
The central goal of crystal engineering is to develop precise control over material function \emph{via} rational design of structure. A particularly successful realisation of this paradigm is theExpand
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Hybrid Perovskites, Metal--Organic Frameworks, and Beyond: Unconventional Degrees of Freedom in Molecular Frameworks.
The structural degrees of freedom of a material are the various distortions most straightforwardly activated by external stimuli. A highly successful design strategy in materials chemistry involvesExpand