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Pressure Effect on the Solvation of Tetraalkylammonium Ions in Water
In order to elucidate the pressure effect on the hydrophobic hydration shell, the limiting molar conductivities of tetraalkylammonium ions (Me4N+ to Bu4N+) in H2O and D2O were determined at 5°C as a
Cyanation of acetals with t-butyl isocyanide-TiCl4 system.
Cyanation of acetals was achieved by t-butyl isocyanide in the presence of TiCl4, producing cyanohydrin ethers in good yields. β-(Trimethylsilyl)ethyl isocyanide in the combination with TiCl4
Brønsted base and acid catalysts, and additional topics
* Authoritative, broad overview of the field, compiled by 38 experts * Critical presentation of the best organocatalytic and related methodologies available today for practical asymmetric synthesis *
Effect of L-leucine-supplemented diet on the nicotinamide adenine dinucleotide content of rat liver.
TLDR
The findings strongly suggest that decrease in the liver NAD content by excess dietary leucine is mainly due to competitive inhibition by L-leucine of intestinal absorption of L-tryptophan.
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