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Artificial hemoglobins have been prepared with Mn(III) and Zn(II) tetrasulfonated phthalocyanines in place of heme. Their structure and properties have been investigated by difference spectroscopy, CD, epr, electrophoresis, and molecular weight estimation. Spectrophotometric titration data indicate the ratio of the reagents in this process to be 1:1. The(More)
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