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The structure and reactivity of a room temperature stable zinc carbonyl complex in Zn-modified H-ZSM-5 zeolite were revealed by solid-state NMR spectroscopy.
The temperature-dependence of the influence of the position-2-methyl group on the structure-directing effect of piperazine in the synthesis of open-framework aluminophosphates was investigated. By heating the initial mixture with the composition of Al2O3:1.5 P2O5:R:125 H2O at 160 °C, where R is the structure-directing agent of 2-methylpiperazine or… (More)
The methanol to olefins conversion over zeolite catalysts is a commercialized process to produce light olefins like ethene and propene but its mechanism is not well understood. We herein investigated the formation of ethene in the methanol to olefins reaction over the H-ZSM-5 zeolite. Three types of ethylcyclopentenyl carbocations, that is, the… (More)
Pedestrian dead reckoning (PDR) is a promising complementary technique to balance the requirements on both accuracy and costs in outdoor and indoor positioning systems. In this paper, we propose a unified framework to comprehensively tackle the three sub problems involved in PDR, including step detection and counting, heading estimation and step length… (More)