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Journals and Conferences
A new class of benzimidazolylidene carbene-Pt(0) complexes was developed and used to efficiently catalyse the hydrosilylation of alkenes.
The regioselective hydrosilylation of terminal and internal alkynes catalyzed by the novel (IPr)Pt(AE) ( 7) (IPr = bis(2,6-diisopropylphenyl)imidazo-2-ylidene, AE = allyl ether) complex is presented.… (More)
With a view to addressing the shortcomings of traditional catalysts, a new generation of outstanding N-heterocyclic carbene platinum(0) complexes for the hydrosilylation of unsaturated carbon-carbon… (More)
Y not? A unique, three-coordinate Y-shaped bis(silyl)platinum(II) complex was isolated and characterized (see structure; C light gray, N blue, Si pink, Pt dark gray). DFT studies on a model system… (More)
Herein, we wish to describe the efficient three-step synthesis of a novel highly hindered, but flexible, N-heterocyclic carbene and its coordination chemistry to Ag(i) and Rh(i).
Alkenyl silanes are efficiently converted to the corresponding silyl cyclopropanes in the presence of a slight excess of diazomethane (2-4 equiv) and a low loading of Pd(OAc)(2) (<0.5 mol %).… (More)