Guang-Jin Chen

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Molecular dynamics simulations were performed for CO2 dissolved in water near silica surfaces to investigate how the hydrophilicity and crystallinity of solid surfaces modulate the local structure of adjacent molecules and the nucleation of CO2 hydrates. Our simulations reveal that the hydrophilicity of solid surfaces can change the local structure of water(More)
The kinetics of film growth of hydrates of methane, ethane, and methane-ethane mixtures were studied by exposing a single gas bubble to water. The morphologies, lateral growth rates, and thicknesses of the hydrate films were measured for various gas compositions and degrees of subcooling. A variety of hydrate film textures was revealed. The kinetics of(More)
Removal of carbon dioxide is an essential step in many energy-related processes. Here we report a novel slurry concept that combines specific advantages of metal-organic frameworks, ion liquids, amines and membranes by suspending zeolitic imidazolate framework-8 in glycol-2-methylimidazole solution. We show that this approach may give a more efficient(More)
Natural gas hydrates are cage-like crystalline compounds in which a large amount of methane is trapped within a crystal structure of water, forming solids at low temperature and high pressure. Natural gas hydrates are widely distributed in permafrost regions and offshore. It is estimated that the worldwide amounts of methane bound in gas hydrates are total(More)
Separation of low boiling gas mixtures is widely concerned in process industries. Now their separations heavily rely upon energy-intensive cryogenic processes. Here, we report a pseudo-absorption process for separating low boiling gas mixtures near normal temperature. In this process, absorption-membrane-adsorption is integrated by suspending suitable(More)
  • Jin-Rong Zhong, Xin-Yang Zeng, Feng-He Zhou, Qi-Dong Ran, Chang-Yu Sun, Rui-Qin Zhong +3 others
  • 2016
The hydrate structure type and dissociation behavior for pure methane and methane-ethane hydrates at temperatures below the ice point and atmospheric pressure were investigated using in situ Raman spectroscopic analysis. The self-preservation effect of sI methane hydrate is significant at lower temperatures (268.15 to 270.15 K), as determined by the stable(More)
  • Zhi Li, Gangqiang Xu, Bei Liu, Xin Lv, Guangjin Chen, Changyu Sun +2 others
  • 2015
As a new branch of MOFs which are composed of biocompatible metal ions and organic ligands, bio-metal-organic frameworks (bio-MOFs) have attracted much attention recently. Bio-MOFs feature multiple Lewis basic sites which have strong interaction with CO2 molecules, thus they have great potential in the separation and purification of gas mixtures containing(More)
Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our(More)
Hydrate formation/dissociation of natural gas in (diesel oil + water) emulsion systems containing 3 wt% anti-agglomerant were performed for five water cuts: 5, 10, 15, 20, and 25 vol%. The natural gas solubilities in the emulsion systems were also examined. The experimental results showed that the solubility of natural gas in emulsion systems increases(More)
The replacement of methane with carbon dioxide in natural gas hydrate-bearing sediments is considered a promising technology for simultaneously recovering natural gas and entrapping CO 2. During the CH 4-CO 2 replacement process, the variations of geophysical property of the hydrate reservoir need to be adequately known. Since the acoustic wave velocity is(More)
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