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Di-μ-perchlorato-bis{μ-2-[(2-pyridyl)methylaminomethyl]phenolato)dicopper(II) acetonitrile disolvate
TLDR
In the crystal of the dinuclear title compound, [Cu2(C13H13N2O)2(ClO4)2]·2CH3CN, the two bridging perchlorate ions chelate to the two CuII atoms in a μ-O:O′ fashion on opposite sides of the equatorial plane. Expand
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Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ4 N,N′,O:O;κ4 O:N,N′,O-bis[(thiocyanato-κN)copper(II)]
TLDR
The centrosymmetric binuclear complex, [Cu2(C13H13N2O)2(NCS)2], formed via phenolate oxygen bridges, involves the CuII atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. Expand
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Di-μ2-acetato-diacetato-bis{μ2-3,3′,5,5′-tetramethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}tricobalt(II,III) dichloromethane disolvate
TLDR
The trinuclear title compound, [Co3(CH3COO)4(C20H22N2O6)2]·2CH2Cl2, contains mixed-valence cobalt ions in the following order CoIII–CoII–CoIII where all the three cobalt ion are hexacoordinated. Expand
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[2,2′-(2,6,9,13-Tetraazatetradecane-1,14-diyl)diphenolato]iron(III) iodide
TLDR
The title FeIII complex, [Fe(C22H32N4O2)]I, contains a six-coordinate FeN 4O2 cation in which the ligand is a reduced Schiff base resulting from the NaBH4 reduction of the condensation product between salicylaldehyde and 1,5,8,12-tetraazadodecane. Expand
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Ethylenediammonium tetrakis({2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)) bis(perchlorate) dimethylformamide monosolvate
TLDR
The title compound, (C2H10N2)[Ni(C16H14N2O2)]4(ClO4)2·C3H7NO, crystallizes with four Ni(salen) molecules {salen is 2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolate}. Expand
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{3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
TLDR
The title square-planar nickel complex, [Ni(C20H22N2O6)], has Ni—N and Ni—O bond lengths of 1.8478 (14) and 1.8520  (12) Å. Expand
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{3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II)
TLDR
In the title square-planar copper complex, [Cu(C20H22N2O6)], the Cu—N and Cu—O bond lengths are significantly longer than those of its isostructural nickel analog. Expand
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3-(4-Chlorobenzenesulfonamido)-5-methylcyclohex-2-en-1-one
TLDR
For the title compound, C13H14ClNO3S, geometrical parameters, determined using X-ray diffraction techniques, are compared with those calculated by density functional theory (DFT), using hybrid exchange-correlation functional, B3LYP methods. Expand
Dibromido(4,7-diazadecane-1,10-diamine)copper(II)
TLDR
In the title compound, [CuBr2(C8H22N4)], the CuII atom is six-coordinate forming a distorted octahedral complex and is bonded to two axial bromide anions and four equatorial nitrogen donors. Expand
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