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This article describes the syntheses of two covalently linked oxygen-bridged hybrid metallocene-nonmetallocene polymetallic catalysts bearing two different catalytically active group 4 metals. The reactions of Cp*2(Me)Zr(OH) (2) with Ti(NMe2)4 and Hf(NMe2)4 led to the formation of a heterobimetallic compound Cp*2(Me)Zr(micro-O)Ti(NMe2)3 (7) and a(More)
A 4-yr study was conducted to determine the effects of two grazing methods (GM) at two stocking rates (SR) on alfalfa pasture plant productivity and animal performance and to ascertain the effect of grazing systems on subsequent performance of steers fed a high-concentrate diet. Eight pasture plots (.76 ha) were seeded in 1988 with alfalfa (Medicago sativa(More)
A first structurally characterized primary aminophosphane (Ar 2PNH 2 ( 2); Ar = 2,4,6- iPr 3C 6H 2) that is a stable solid at room temperature without decomposition by self-condensation is reported. Reactions of N-phosphanyllithium amide ( tBu 2PNHLi ( 3)) with Me 2SiCl 2 and MeSiCl 3 in Et 2O result in the formation of Me 2Si(NHP tBu 2) 2 ( 4) and MeSi(NHP(More)
The diisopropylphosphanyl-substituted anthracenes i-Pr2P(C14H9) (1a), i-Pr2P(C14H8)Br (2a), and (i-Pr2P)2(C14H8) (3a) and some of their oxidation products were prepared from 9-bromoanthracene and 9,10-dibromoanthracene, respectively. Low-temperature (1)H NMR spectra of the 9-monophosphanyl-substituted anthracenes 1a and 2a are in accordance with a staggered(More)
Herein we report on the reactivity of the stable germanium(II) hydride LGeH (L = CH{(CMe)(2,6-iPr(2)C(6)H(3)N)}(2)) (2), which contains a low-valent germanium atom. 2 is prepared from the corresponding germanium(II) chloride LGeCl (1) using H(3)Al x NMe(3) or K[HB(iBu)(3)] in toluene. The reaction of 2 with carbon dioxide in toluene at room temperature(More)
The use of Raman spectroscopy for on-line monitoring of the production of superconducting YBa2Cu3O6+X (YBCO) thin films on long-length metal tapes coated with textured buffer layers is reported for the first time. A methodology is described for obtaining Raman spectra of YBCO on moving tape exiting a metal-organic-chemical-vapor-deposition (MOCVD)(More)