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2005

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Using density functional theory in the modified mean-field (MMF) approximation we study the phase behavior of asymmetric binary mixtures of equisized dipolar hard spheres with different dipole moments in the fluid phase regime. We focus on "dipole-dominated" systems where isotropic attractive interactions are absent. Despite these restrictions our results… (More)

Using reference hypernetted chain (RHNC) integral equations and density functional theory in the modified mean-field (MMF) approximation we investigate the phase behavior of binary mixtures of dipolar hard spheres. The two species (A and B) differ only in their dipole moments m(A) and m(B), and the central question investigated is under which conditions… (More)

We present phase diagrams of a model bidisperse ferrocolloid consisting of a binary mixture of dipolar hard spheres (DHSs) under the influence of an external magnetic field. The dipole moments of the particles are chosen proportional to the particle volume to mimic real ferrocolloids, and we focus on dipole-dominated systems where isotropic attractive… (More)

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