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An enantiospecific total synthesis of (-)-patchouli alcohol
An enantiospecific total synthesis of patchouli alcohol, starting from the readily available monoterpene (R)-carvone, has been accomplished. A tandem double Michael reaction-alkylation sequence andExpand
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Transition metals catalyzed C–C and C–O bonds formation: facile synthesis of flavans and benzoxepines
Abstract A simple and practical method has been developed based on intermolecular [Pd]-catalyzed C–C and an intramolecular [Cu]-catalyzed C–O bond formations for the synthesis of flavans andExpand
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The first enantiospecific total synthesis of (+)-seychellene
The first enantiospecific total synthesis of the tricyclic sesquiterpene (+)-seychellene, starting from (R)-carvone via (S)-3-methylcarvone, has been accomplished employing a combination of anExpand
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Total Synthesis of (±)‐Infuscol A and (±)‐Cuprenenol
Abstract Total synthesis of the nonaromatic cuparenoid sesquiterpenes (±)‐infuscol A and cuprenenol, and (±)‐infuscol B and neocuprenenol isolated from the Japanese liverwort Jungermannia infusca hasExpand
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Enantioselective formal total syntheses of Clavukerin A and isoclavukerin A via a ring-closing metathesis reaction
Enantioselective formal total syntheses of the marine trisnorsesquiterpenes clavukerin A and isoclavukerin A, starting from (R)-limonene employing an RCM reaction as the key step, are described.
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A biogenetically patterned enantiospecific synthesis of allopupukeanones
The first enantiospecific synthesis of allopupukeanones has been accomplished starting from 6-methylcarvone. A biogenetically patterned rearrangement of a pupukeanane to allopupukeanane was employedExpand
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Chiral synthons from α-pinene: enantioselective syntheses of bicyclo[3.3.0] and [3.2.1]octanones
Abstract Enantioselective syntheses of bicyclo[3.3.0]octan-3-one, bicyclo[3.2.1]octan-3-one and bicyclo[3.2.1]octan-2-one derivatives were accomplished by employing a chiron based approach, usingExpand
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