• Publications
  • Influence
Cr K‐Edge XANES Spectroscopy: Ligand and Oxidation State Dependence — What is Oxidation State?
A series of Cr complexes varying in oxidation state, ligand and geometry were studied with Cr K‐edge XANES. The main absorption edge energy shift for an oxidation state change from Cr0 to Cr6+ isExpand
  • 35
  • 2
  • Open Access
Multinuclear NMR studies of diphosphine, diphosphine–dioxide and diarsine complexes of tin(IV) halides. Structures of [SnI4{o-C6H4(AsMe2)2}] and [SnI4{o-C6H4(P(O)Ph2)2}]
The complexes [SnX4(L–L)] (X=Cl or Br, L–L=Me2PCH2CH2PMe2, Ph2PCH2CH2PPh2, o-C6H4(PPh2)2, o-C6H4(AsMe2)2, Ph2AsCH2CH2AsPh2) have been isolated from reaction of SnX4 with the ligand in anhydrousExpand
  • 31
  • 2
Highly Selective Chemical Vapor Deposition of Tin Diselenide Thin Films onto Patterned Substrates via Single Source Diselenoether Precursors
The distorted octahedral complexes [SnCl4{nBuSe(CH2)nSenBu}] (n = 2 or 3), (1) and (2), obtained from reaction of SnCl4 with the neutral bidentate ligands and characterized by IR/Raman andExpand
  • 38
  • 1
  • Open Access
Platinum metal thioether macrocyclic complexes: synthesis, electrochemistry, and single-crystal X-ray structures of cis-[RhCl2L2]PF6 and trans-[RhCl2L3]PF6(L2= 1,4,8,11 -tetrathiacyclotetradecane,
Reaction of RhCl3 with 1 mol equivalent of L[1,4,7,10-tetrathiacyclododecane (L1), 1,4,8,11-tetrathiacyclotetradecane (L2), and 1,5,9,13-tetrathiacyclohexadecane (L3)] in refluxing MeOH affords theExpand
  • 22
  • 1
Hybrid Dibismuthines and Distibines: Preparation and Properties of Antimony and Bismuth Oxygen, Sulfur, and Nitrogen Donor Ligands
The hybrid dibismuthines O{(CH2)2BiPh2}2, MeN(CH2-2-C6H4BiR2)2, and S(CH2-2-C6H4BiR2)2 (R = Me, Ph), have been prepared and characterized by microanalysis, 1H and 13C{1H} NMR spectroscopy, and FABExpand
  • 23
  • 1
The Crystal Structure and Raman Spectrum of Ge5Cl12·GeCl4 and the Vibrational Spectrum of Ge2Cl6
The Raman spectrum of Ge2Cl6 shows close analogies with that of the isoelectronic [Ga2Cl6]2-. A band at 262 cm-1 is assigned as principally a Ge−Ge stretching mode. The compound is veryExpand
  • 20
  • 1
Complexes of aluminium, gallium and indium trifluorides with neutral oxygen donor ligands: Synthesis, properties and reactions
Abstract The MF3·3H2O (M = Al, Ga or In) dissolve in hot dimethylsulfoxide (dmso) to form [MF3(OH2)2(dmso)]; further dmso is not incorporated even after prolonged reflux. The X-ray structure ofExpand
  • 15
  • 1
  • Open Access
Synthesis, spectroscopic and structural characterization of PdII and PtII complexes of the cyclic diselenoether 1,5-diselenacyclooctane, [8]aneSe2
Abstract The complexes [M([8]aneSe2)Cl2] and [M([8]aneSe2)2][PF6]2 [M = Pd or Pt, [8]aneSe2= have been prepared, and characterized by analysis, UV-vis and multinuclear (1H, 77Se{1H} and 195Pt) NMRExpand
  • 28
  • 1
Synthesis and properties of Rh(I) and Ir(I) distibine complexes with organometallic co-ligands.
The first series of Rh(I) distibine complexes with organometallic co-ligands is described, including the five-coordinate [Rh(cod)(distibine)Cl], the 16-electron planar cations [Rh(cod)(distibine)]BF4Expand
  • 12
  • 1