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Absolute ν2 Line Intensities of HOCl by Simultaneous Measurements in the Infrared with a Tunable Diode Laser and Far-Infrared Region Using a Fourier Transform Spectrometer
Abstract We have measured absolute line intensities in the ν 2 fundamental band at 1238 cm −1 of both isotopomers of hypochlorous acid, HOCl. To obtain the partial pressure of the species in theExpand
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Global analysis of high resolution infrared and rotational spectra of HCCC15N up to 1335 cm−1
The rotational spectrum of an enriched sample of (HCCCN)-N-15 was measured from 200 to 1200 GHz. The high-resolution infrared spectrum was also measured from 160 to 11000cm(-1). Several thousands ofExpand
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Synthesis and properties of the tetrakis(trifluoromethyl)borate anion, [b(CF3)4]-: structure determination of Cs[B(CF3)4] by single-crystal X-ray diffraction.
Salts of the tetrakis(trifluoromethyl)borate anion, M[B(CF3)4], M=Li, K, Cs, Ag, have been prepared by two different routes for the first time. The colorless compounds are thermally stable up to 425Expand
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Zur Heterogenität von Enzymen
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Syntheses and characterization of (C2F5)3BCO and (C3F7)3BCO.
The new tris(perfluoroalkyl)borane carbonyls, (C(2)F(5))(3)BCO and (C(3)F(7))(3)BCO, were prepared by means of a novel synthetic route using commercially available precursors by reactingExpand
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Perfluoroalkyl borates: congeners of perfluoroalkanes
Abstract This review describes the synthesis and properties of borates that carry CF 3 (or more generally, perfluoroalkyl R f ) groups bonded to boron. Some novel amine-boranes R(CF 3 ) 2 B·NHMe 2Expand
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NOVEL 2 + 2 CYCLOADDITION REACTIONS OF (DIMETHYLAMINO)BIS(TRIFLUOROMETHYL)BORANE, (CF3)2BNME2, WITH N-SULFINYLSULFONAMIDES, AMINOIMINOPHOSPHINES, CARB ODIIMIDES, AND A KETENEIMINE
(Dimethylamino)bis(trifluoromethyl)borane, (CF3)2BNMe2 (1), combines with N-sulfinylsulfonamides RO2SNSO in a [2 + 2] fashion (R = Me (2a), Et (2b), iPr (2c), Ph (2d), and pTol (2e)).Expand
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Tetrakis(dimethylamino)ethylene/trifluoroiodomethane. a specific novel trifluoromethylating agent
Abstract At low temperatures tetrakis(dimethylamino)ethylene (I) and CF3I form a charge transfer complex, which can act as a nucleophilic trifluoromethylating agent in polar solvents according toExpand
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Reaction of tetrakis(dimethylamino)ethylene with CF2Br2 in the presence of secondary amines, formation of N-trifluoromethyl-dialkylamines
Abstract N-trifluoromethylamines of the general formula R 2 NCF 3 (R= Me (I),Et (II), i-Pr (III), i-Bu (IV); 2R = (CH 3 ) 2 C-(CH 2 ) 3 -C(CH 3 ) 2 (V) and(CH 2 ) 6 (VI) ) have been obtained from theExpand
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