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Small-molecule inhibition of APT1 affects Ras localization and signaling.
TLDR
This work presents the knowledge-based development and characterization of a potent inhibitor of acyl protein thioesterase 1 (APT1), a bona fide depalmitoylating enzyme that is, so far, poorly characterized in cells.
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Polymerization of lactide with zinc and magnesium beta-diiminate complexes: stereocontrol and mechanism.
TLDR
The substituents on the beta-diiminate ligand exert a significant influence upon the course of the polymerizations, affecting both the degree of stereoselectivity and the rate of polymerization.
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Cobalt catalysts for the alternating copolymerization of propylene oxide and carbon dioxide: combining high activity and selectivity.
TLDR
An unprecedented catalytic activity of 620 turnovers per hour is achieved for the copolymerization of rac-PO and CO(2), yielding iso-enriched PPC with 94% head-to-tail connectivity and an unreported PPC microstructure.
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Suppression of lithium dendrite growth using cross-linked polyethylene/poly(ethylene oxide) electrolytes: a new approach for practical lithium-metal polymer batteries.
TLDR
The results suggest that a high-modulus SPE is not a requirement for the control of dendrite proliferation, and a cross-linked polyethylene/poly(ethylene oxide) SPE with both high ionic conductivity and excellent resistance to dendrites growth is reported.
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Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides with Discrete Metal Complexes: Structure-Property Relationships.
TLDR
A perspective on the current state of the field of epoxide/anhydride copolymerization mediated by discrete catalysts and the relationships between the structures and properties of these polyesters are given.
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Mechanism of the alternating copolymerization of epoxides and CO2 using beta-diiminate zinc catalysts: evidence for a bimetallic epoxide enchainment.
TLDR
It is proposed that two zinc complexes are involved in the transition state of the epoxide ring-opening event and rate studies on the copolymerization exhibit no dependence in CO(2), a first-order dependence in [CHO], and orders in [Zn](tot) ranging from 1.0 to 1.8 for [(BDI)ZnOAc] complexes.
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Alternating copolymerization of limonene oxide and carbon dioxide.
TLDR
The alternating copolymerization of (R)- or (S)-limonene oxide and CO2 using beta-diiminate zinc acetate catalysts is reported, which exhibits a high selectivity for the trans isomer and produces regioregular polycarbonate.
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A scanning tip electrospinning source for deposition of oriented nanofibres
We present a method for controlled deposition of oriented polymeric nanofibres. The method uses a microfabricated scanned tip as an electrospinning source. The tip is dipped in a polymer solution to…
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Precise control of polyolefin stereochemistry using single-site metal catalysts.
  • G. Coates
  • Chemistry
    Chemical reviews
  • 25 March 2000
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Imidazolium Cations with Exceptional Alkaline Stability: A Systematic Study of Structure-Stability Relationships.
TLDR
Imidazolium cations are synthesized and characterized that have the highest alkaline stabilities reported to date, >99% cation remaining after 30 days in 5 M KOH/CD3OH at 80 °C.
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