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Molecular Nanomagnets
Quantum mechanical tunneling of the direction of magnetization is discussed for several examples of single-molecule magnets (SMM's). Magnetization tunneling is described for two crystallographicallyExpand
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
The syntheses and electrochemical and magnetochemical properties of [Mn 12 O 12 (O 2 CPh) 16 (H 2 O) 4 ] (3), its solvate 3.PhCOOH-CH 2 Cl 2 , and [Mn 12 O 12 (O 2 CMe) 16 (H 2 O) 4 ].MeCOOH-3H 2 OExpand
Exchange-biased quantum tunnelling in a supramolecular dimer of single-molecule magnets
Various present and future specialized applications of magnets require monodisperse, small magnetic particles, and the discovery of molecules that can function as nanoscale magnets was an importantExpand
The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4].
Single-molecule magnets (SMMs) are individual molecules that can function as nanoscale magnetic particles. The [Mn12O12(O2CR)16(H2O)4] (Mn12; R=Me, Et, etc.) family of SMMs was the first oneExpand
On-chip SQUID measurements in the presence of high magnetic fields.
We report a low temperature measurement technique and the magnetization data of a quantum molecular spin, by implementing an on-chip SQUID technique. This technique enables SQUID magnetometry in highExpand
A new model for the structure of the DACs regions in the Oe and Be stellar atmospheres
As it is already known, the spectra of many Oe and Be stars present Discrete Absorption Components (DACs) which, because of their profiles' width as well as the values of the expansion / contractionExpand
Single-Molecule Magnets
Magnets are widely used in a large number of applications, and their market is larger than that of semiconductors. Information storage is certainly one of the most important uses of magnets, and theExpand
Giant single-molecule magnets: a [Mn84] torus and its supramolecular nanotubes.
The discovery that individual molecules can function as magnets provided a new, ‘bottom-up’ approach to nanoscale magnetic materials, and such molecules have since been ____________________ [*] Prof.Expand
Synthetic model of the asymmetric [Mn3CaO4] cubane core of the oxygen-evolving complex of photosystem II
The laboratory synthesis of the oxygen-evolving complex (OEC) of photosystem II has been the objective of synthetic chemists since the early 1970s. However, the absence of structural information onExpand
The electronic structure of Mn in oxides, coordination complexes, and the oxygen-evolving complex of photosystem II studied by resonant inelastic X-ray scattering.
Resonant inelastic X-ray scattering (RIXS) was used to collect Mn K pre-edge spectra and to study the electronic structure in oxides, molecular coordination complexes, as well as the S1 and S2 statesExpand