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(␮-O) 2 in superoxidized manganese catalase has been suggested as the basis for inactivity of this oxidation state; G. argued against a Mn valence change on S 2 3 S 3 , and Yachandra et al. (4) have proposed that one-electron oxidation of the bridging oxo group (or groups) occurs. However, a similar bridging oxyl ligand formulation for intermediate X in(More)
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