Fu-Pei Liang

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Highly luminescent zinc(II)-bis(8-hydroxyquinoline) (Znq(2)) complex nanorods have been synthesized via a sonochemical route from the microemulsion containing zinc acetate and 8-hydroxyquinoline. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images showed that the products were rod-like morphology with a diameter of about(More)
The reaction of M(II) ions with azido ligands in the presence of different amino carboxylic acids gave four three-dimensional metal-azido coordination polymers, [Mn(3,5-daba)(N(3))](n) (1), [Cd(3,5-daba)(N(3))](n) (2; 3,5-daba = 3,5-diaminobenzoate), [Mn(4-aba)(N(3))](n) (3; 4-aba = 4-aminobenzoate), and [Cu(2)(gly)(2)(N(3))(2)](n) (4; gly = glycinate),(More)
In the title compound, {[Co(C7H7N2O2)2].H2O}n, the CoII atom lies on an inversion centre and has octahedral geometry, defined by two O atoms in axial positions and four N atoms in equatorial sites from six different 3,5-diaminobenzoate ligands. Each 3,5-diaminobenzoate anion acts as a mu3-bridging ligand, linking three adjacent CoII ions through one O atom(More)
An unprecedented {Gd18} nanowheel was solvothermally synthesized with a novel diacylhydrazone ligand. It features a rare single-stranded skeleton just like a Reuleaux triangle with vertices buckled in, represents the highest nuclearity and largest size in lanthanide (Ln) wheels reported so far, and shows a large magnetocaloric effect (MCE).
A series of Ln4 clusters, [Ln4L2(μ3-OH)2(μ4-NO3)(NO3)4(OCH3)(H2O)]·xMeCN·yMeOH (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5), Yb (6), L = 2-{[2-(2-hydroxy-ethoxy)-ethylimino]-methyl}-6-methoxyphenol), have been synthesized by the reaction of Ln(NO)3 and a Schiff-base ligand formed in situ. The six complexes display similar structures, with an overall metal(More)
Six transition metal coordination polymers, [Cu(3)(nbta)(2)(bipy)(2)(H(2)O)(2)] x 2 H(2)O (1), [Cu(3)(nbta)(2)(bpp)(2)(H(2)O)(2)] x 2 H(2)O (2), [Co(3)(nbta)(2)(bipy)(3)(H(2)O)(2)] x 2 H(2)O (3), [Co(3)(nbta)(2)(bpp)(2)(H(2)O)(2)] (4), [Ni(2)(Hnbta)(2)(bipy)(2)(H(2)O)(2)] (5) and [Ni(3)(nbta)(2)(bpa)(3)(H(2)O)(2)] x 2 H(2)O (6) (H(3)nbta =(More)
In the title compound, [Gd(C(8)H(6)NO(2))(3)(H(2)O)](n), the gadolinium(III) ion is coordinated by eight carboxyl-ate O atoms and one water mol-ecule. The carboxyl-ate ligands bridge pairs of gadolinium(III) ions, forming a zigzag chain along [100]. Hydrogen bonds link the chains into sheets parallel to (001).
The title compound, [Mn7(C2H2N3)8(C2H3O2)4(OH)2]n, is composed of centrosymmetric heptanuclear building units with the central Mn atom on an inversion center. In the building block, three Mn(II) ions are held together by one mu3-hydroxide group, two mu2-triazolate (trz) ligands and two mu2-acetate groups, forming an Mn3 cluster. Two Mn3 clusters are bridged(More)
Nanospheric hydroxo-bridged clusters of [M(20)(OH)(12)(maleate)(12)(Me(2)NH)(12)](BF(4))(3)(OH)·nH(2)O (M = Co (1), Ni (2)) with O(h) symmetry were afforded under hydrothermal condition with Co(BF(4))(2)·6H(2)O/Ni(BF(4))(2)·6H(2)O and fumaric acid in a DMF/EtOH mixed solvent. They are characterized by elemental analysis, IR, and X-ray diffraction. X-ray(More)
The syntheses, structures, and characterization of four 3d-4f butterfly clusters are described. With different polyhydroxy Schiff-base ligands 2-(((2-hydroxy-3-methoxyphenyl)methylene)amino)-2-(hydroxymethyl)-1,3-propanediol (H4L1) and 2-(2,3-dihydroxpropyliminomethyl)-6-methoxyphenol (H3L2), three heterotetranuclear NiLn complexes (NiDy-L1 (1), NiTb-L2(More)