Frank Mares

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Cobalt-Nitro Complexes as Palladium Oxidants. Cobalt-nitro complexes I and I1 are very weak nucleophiles. Therefore, the presence of almost any other competing nucleophile in the above system should result in Wacker-type chemistry. Thus, in acetic acid (Table I, run 7), vinyl acetate is the sole product when ethylene is oxidized by a mixture of cobalt-nitro(More)
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