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Optical characterizations of YCa4O(BO3)3 and Nd:YCa4O(BO3)3 crystals
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Synthesis of Discodermolide
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Total syntheses of amphidinolides B1, B4, G1, H1 and structure revision of amphidinolide H2.
TLDR
A robust, convergent and hence general blueprint is described which allowed not only to conquest five prototype members of these series, but also holds the promise of making "non-natural" analogues available by diverted total synthesis.
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Total syntheses of amphidinolide H and G.
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Selective unusual Pd-mediated biaryl coupling reactions: solvent effects with carbonate bases.
A one-step Pd-catalyzed reaction performed on an o-bromobenzamide permitted the selective formation of either phenanthridinones 2 via an ipso substitution or new phenanthridinone-1-carboxamides 3…
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Synthesis and biological evaluation of N-substituted benzo[c]phenanthrolines and benzo[c]phenanthrolinones as antiproliferative agents.
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The isolation and synthesis of neodolastane diterpenoids.
TLDR
The aim of this account is to summarise the progress in the isolation, characterisation and synthesis of these diterpenoids as well as to review their biogenetic origins and diverse biological activities since their discovery in 2000.
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alpha-Oxygenated crotyltitanium and dyotropic rearrangement in the total synthesis of discodermolide.
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Total synthesis of discodermolide: optimization of the effective synthetic route.
TLDR
An efficient and modulable total synthesis of discodermolide (DDM), a unique marine anticancer polyketide is described including related alternative synthetic approaches to allow high and reliable yields.
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Synthesis and biological evaluation of dialkylaminoalkylamino benzo[c][1,7] and [1,8]phenanthrolines as antiproliferative agents.
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