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TECHNOLOGY UPDATE: Development of a gas-phase bioprocess for isoprene-monomer production using metabolic pathway engineering
- G. Whited, F. Feher, K. Sanford
- Engineering
- 23 June 2010
TLDR
Silsesquioxanes as models for silica surfaces
- F. Feher, D. Newman, John F. Walzer
- Chemistry, Physics
- 1 March 1989
The hydrolytic condensation of cyclohexyltrichlorosilane (CySiCl/sub 3/) affords (Cy/sub 7/Si/sub 7/O/sub 9/(OH)/sub 3/) (1), (Cy/sub 6/Si/sub 6/O/sub 9/) (2), and (Cy/sub 8/Si/sub 8/O/sub…
Kinetics and mechanism of hydrolysis of chloro-1,3,5-triazines. Atrazine
- Steven J. Plust, J. Loehe, F. Feher, J. Benedict, H. F. Herbrandson
- Chemistry
- 1 August 1981
A new route to incompletely-condensed silsesquioxanes: base-mediated cleavage of polyhedral oligosilsesquioxanes
- F. Feher, Raquel Terroba, J. Ziller
- Chemistry
- 1999
Readily available R8Si8O12 frameworks react selectively with aqueous Et4NOH to afford discrete incompletely-condensed silsesquioxanes: reaction of R8Si8O12 (2a, R = c-C6H11; 2b, R = Bui) with Et4NOH…
Practical methods for synthesizing four incompletely condensed silsesquioxanes from a single R8Si8O12 framework
- F. Feher, D. Soulivong, Frank Nguyen
- Chemistry
- 1998
The reaction of (c-C6H11)8Si8O12 1 with triflic acid (TfOH) can produce two different ditriflates with the formula (c-C6H11)8Si8O11(OTf)2, which can be hydrolyzed selectively to four different…
Syntheses of highly functionalized cube-octameric polyhedral oligosilsesquioxanes (R8Si8O12)
- F. Feher, K. Wyndham, D. Soulivong, Frank Nguyen
- Chemistry
- 1999
Reactions of [H2N(CH2)3]8Si8O12 or its octahydrochloride salt with a variety of electrophiles, including anhydrides, lactones, acid chlorides, α,β-unsaturated esters and isocyanates, afforded…
Polyhedral oligometallasilsesquioxanes (POMSS) as models for silica-supported transition-metal catalysts. Synthesis and characterization of (C5Me5)Zr[(Si7O12)(c-C6H11)7]
- F. Feher
- Chemistry
- 1 June 1986
Controlled cleavage of R8Si8O12 frameworks: a revolutionary new method for manufacturing precursors to hybrid inorganic–organic materials
- F. Feher
- Materials Science
- 1998
Cube-octameric polyhedral silsesquioxanes (R8Si8O12) react with strong acids (HX) to produce R8Si8O11X2 frameworks resulting from selective cleavage of one Si–O–Si linkage; subsequent hydrolysis…
Methods for effecting monofunctionalization of (CH2CH)8Si8O12
- F. Feher, K. Wyndham, Richard K. Baldwin, D. Soulivong, J. Ziller, J. Lichtenhan
- Chemistry
- 1999
A new method is described for effecting selective monofunctionalization of CH2CH)8Si8O12 2: reaction of 2 with triflic acid (TfOH) produces (TfOCH2CH2)(CH2 CH)7Si8O12 3, which reacts with…
A new route to incompletely condensed silsesquioxanes: acid-mediated cleavage and rearrangement of (c-C6H11)6Si6O9 to C2-[(c-C6H11)6Si6O8X2]
- F. Feher, Frank Nguyen, D. Soulivong, J. Ziller
- Chemistry, Materials Science
- 1999
Acid-mediated cleavage and rearrangement of (c-C6H11)6Si6O9 1 by triflic acid (TfOH) and methanesulfonic acid (MsOH) produces good yields of C2-[(c-C6H11)6Si6O8X2] (4a, X = OTf; 4b, X = MsO), which…
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