Author pages are created from data sourced from our academic publisher partnerships and public sources.
- Publications
- Influence
Kinetic evidence for a tetrameric transition state in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes.
- F. Buono, D. Blackmond
- Chemistry, Medicine
- Journal of the American Chemical Society
- 2 July 2003
Experimental kinetic data coupled with kinetic modeling implicates a tetrameric transition state in the Soai autocatalytic alkylation of pyrimidyl aldehydes. The kinetic model accurately predicts… Expand
Efficient Iron‐Catalyzed Kumada Cross‐Coupling Reactions Utilizing Flow Technology under Low Catalyst Loadings
- F. Buono, Y. Zhang, +7 authors C. Senanayake
- Chemistry
- 1 May 2016
An efficient continuous flow iron-catalyzed Kumada cross-coupling was developed for the coupling of 2-chloropyrazine and various aryl Grignard reagents in presence of low catalyst loadings (0.5… Expand
Insights into palladium-catalyzed cyanation of bromobenzene: additive effects on the rate-limiting step.
- F. Buono, Rama Chidambaram, R. Mueller, R. Waltermire
- Chemistry, Medicine
- Organic letters
- 4 November 2008
Kinetic studies using reaction calorimetry were conducted under synthetically relevant conditions to study the effect of additives in the cyanation of bromobenzene catalyzed by palladium complexes.… Expand
Transnitrilation from Dimethylmalononitrile to Aryl Grignard and Lithium Reagents: A Practical Method for Aryl Nitrile Synthesis.
- J. T. Reeves, Christian A Malapit, +6 authors C. Senanayake
- Chemistry, Medicine
- Journal of the American Chemical Society
- 15 July 2015
An electrophilic cyanation of aryl Grignard or lithium reagents, generated in situ from the corresponding aryl bromides or iodides, by a transnitrilation with dimethylmalononitrile (DMMN) was… Expand
Remarkable beta-selectivity in the synthesis of beta-1-C-arylglucosides: stereoselective reduction of acetyl-protected methyl 1-C-arylglucosides without acetoxy-group participation.
- P. Deshpande, B. Ellsworth, +7 authors R. Mueller
- Chemistry, Medicine
- The Journal of organic chemistry
- 13 November 2007
An efficient and practical process to generate beta-C-arylglucoside derivatives was achieved. The process described involves Lewis acid mediated ionic reduction of a peracetylated 1-C-aryl methyl… Expand
Physical and chemical rationalization for asymmetric amplification in autocatalytic reactions.
- F. Buono, H. Iwamura, D. Blackmond
- Chemistry, Medicine
- Angewandte Chemie
- 13 April 2004
Synthesis of the 6-azaindole containing HIV-1 attachment inhibitor pro-drug, BMS-663068.
- K. Chen, Christina A. Risatti, +12 authors Martin D Eastgate
- Chemistry, Medicine
- The Journal of organic chemistry
- 5 September 2014
The development of a short and efficient synthesis of a complex 6-azaindole, BMS-663068, is described. Construction of the 6-azaindole core is quickly accomplished starting from a simple pyrrole, via… Expand
A Practical Stereoselective Synthesis and Novel Cocrystallizations of an Amphiphatic SGLT-2 Inhibitor
- P. Deshpande, J. Singh, +25 authors R. Mueller
- Chemistry
- 28 March 2012
A practical synthesis of the SGLT-2 inhibitor β-C-aryl-d-glucoside (1) has been developed. The route employed 2,3,4,6-tetra-O-trimethlysilyl-d-glucano-1,5-lactone as the key chiral building block,… Expand
Oxidative dehydrogenation of dihydropyrimidinones and dihydropyrimidines.
- K. Yamamoto, Y. Chen, F. Buono
- Chemistry, Medicine
- Organic letters
- 13 September 2005
[reaction: see text] A mild, practical procedure for oxidative dehydrogenation with catalytic amounts of a Cu salt, K2CO3, and tert-butylhydroperoxide (TBHP) as a terminal oxidant has been developed.… Expand
Rationalization of anomalous nonlinear effects in the alkylation of substituted benzaldehydes.
- F. Buono, P. Walsh, D. Blackmond
- Chemistry, Medicine
- Journal of the American Chemical Society
- 24 October 2002
Anomalous nonlinear effects in the alkylation of substituted benzaldehydes with diethylzinc using aminoalcohol catalysts are rationalized in terms of a simple extension of the Noyori model to allow… Expand
...
1
2
3
4
...