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Multifunctional metal-organic frameworks: from academia to industrial applications.
This review exhaustively review the many efforts of several worldwide commercial companies to bring functional MOFs towards the daily use and summarise the state-of-the-art on the preparation of promising (multi)functional MOFs in worldwide laboratories and their use as materials for industrial implementation. Expand
Structural and photoluminescence studies of a europium(III) tetrakis(beta-diketonate) complex with tetrabutylammonium, imidazolium, pyridinium and silica-supported imidazolium counterions.
Tetrakis(naphthoyltrifluoroacetonato)lanthanate(III) complexes (Ln = Eu, Gd) containing the cations tetrabutylammonium, [NBu(4)](+); 1-butyl-3-methylimidazolium, [C(4)mim](+); andExpand
Spectroscopic study of a UV-photostable organic-inorganic hybrids incorporating an Eu3+ beta-diketonate complex.
New europium and gadolinium tris-beta-diketonate complexes have been prepared and incorporated in sol-gel-derived organic-inorganic hybrids, named di-ureasils, which suggest an effective hybrid host-metal ion interaction and an active energy-transfer channel between the hybrid host and the Eu3+ complex. Expand
Chemical evaluation of hypothetical uninodal zeolites.
Optimized structural parameters, framework energies relative to alpha-quartz, and volumes accessible to sorption have been calculated for the systematically enumerated hypothetical uninodal zeolitic structures, which will assist in the design of new synthetic routes and in the identification of newly synthesized materials. Expand
Near-infrared luminescent and magnetic cyano-bridged coordination polymers Nd(phen)n(DMF)m[M(CN)8] (M = Mo, W).
New cyano-bridged coordination polymers have one-dimensional structures with variable number of phenanthroline ligands and exhibit photoluminescence in the near-infrared region and ferromagnetic Nd(3+)-M(5+) interactions. Expand
Montelukast medicines of today and tomorrow: from molecular pharmaceutics to technological formulations
The review describes the emerging delivery strategies to circumvent the current limitations to the use of montelukast that are expected to ultimately lead to the development of more patient-compliant dosage forms. Expand
Near-Infrared Ratiometric Luminescent Thermometer Based on a New Lanthanide Silicate.
Na2 K[(Lu0.75 Yb0.20 Er0.05 )3 Si6 O18 ] is the first example of a lanthanide silicate operative as a near-infrared ratiometric luminescent thermometer, with good sensitivity at cryogenic temperatures (<100 K). Expand
The asymmetric unit of the title compound, C36H24N6, comprises a whole molecule that is tilted with respect to the two pyridine substituents, subtending angles of 36.17 (11) and 34.95  (11)°. Expand
catena-Poly[[triaquachlorido-μ3-malonato-cerium(III)] hemihydrate]
The asymmetric unit of the title compound contains a Ce3+ atom coordinated by a chloride anion, three water molecules and a malonate ligand, and one water molecule of crystallization with a factor of occupancy of 50%. Expand
5-Amino-1H-1,2,4-triazol-4-ium-3-carboxylate hemihydrate
The asymmetric unit of the title compound, C3H4N4O2·0.5H2O, comprises two whole molecules of 5-amino-1H-1,2,4-triazole-3-carboxylic acid in its zwitterionic form, plus one water molecule of crystallization. Expand