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Herein, the structure resulting from in situ turnover in a chemically challenging quaternary ammonium oxidative demethylation reaction was captured via crystallographic analysis and analyzed via single-crystal spectroscopy. Crystal structures were determined for the Rieske-type monooxygenase, stachydrine demethylase, in the unliganded state (at 1.6 Å(More)
To cope with data communication explosion, the alternative, “D2D communication” which enables mobile devices to communicate each other without base station is studied. D2D providing service at a lower cost than cellular network is advantageous for user and also helpful when infra system is out of order by natural disaster. Even if D2D(More)
X-ray free-electron lasers (XFELs) provide very intense X-ray pulses suitable for macromolecular crystallography. Each X-ray pulse typically lasts for tens of femtoseconds and the interval between pulses is many orders of magnitude longer. Here we describe two novel acoustic injection systems that use focused sound waves to eject picoliter to nanoliter(More)
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