Ester Fjellander

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Free energy barriers to biaryl tropoinversion in metal complexes with tropos phosphepine and azepine ligands were determined by temperature-dependent (31)P NMR inversion-transfer experiments and line shape analysis of the temperature-dependent (1)H NMR spectra, respectively. The barrier in the PdCl(2) complex of the azepine ligand was found to be slightly(More)
Pd(II) allyl and Pd(0) olefin complexes containing the configurationally labile ligand 1,2-bis-[4,5-dihydro-3H-dibenzo[c-e]azepino]ethane were studied as models for intermediates in Pd-catalyzed allylic alkylations. According to NMR and DFT studies, the ligand prefers C(s) conformation in both eta3-1,3-diphenylpropenyl and eta3-cyclohexenyl Pd(II)(More)
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