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Kinetics of proton-coupled electron-transfer reactions to the manganese-oxo "cubane" complexes containing the Mn4O4(6+) and Mn4O4(7+) core types.

• Marcelino Maneiro, Wolfgang F. Ruettinger, Emilie Bourlès, George L. McLendon, Gary Dismukes
• Proceedings of the National Academy of Sciences…
• 2003

The kinetics of proton-coupled electron-transfer (pcet) reactions are reported for Mn(4)O(4)(O(2)PPh(2))(6), 1, and [Mn(4)O(4)(O(2)PPh(2))(6)](+), 1(+), with phenothiazine (pzH). Both pcet reactions… (More)

Direct synthesis of a thiolato-S and sulfinato-S Co(III) complex related to the active site of nitrile hydratase: a pathway to the post-translational oxidation of the protein.

• Emilie Bourlès, Rodolphe Alves de Sousa, Erwan Galardon, Michel Giorgi, Isabelle Artaud
• Angewandte Chemie
• 2005

Oxidation of Zn(Cys)4 zinc finger peptides by O2 and H2O2: products, mechanism and kinetics.

• Emilie Bourlès, Manon Isaac, Colette Lebrun, J. F. Latour, Olivier Sénèque
• Chemistry
• 2011

The reactivity of a series of Zn(Cys)(4) zinc finger model peptides towards H(2)O(2) and O(2) has been investigated. The oxidation products were identified by HPLC and ESI-MS analysis. At pH<7.5, the… (More)

Metalation of cyclic pseudopeptidic thiosulfinates with Ni(II) and Zn(II) after ring opening: a mechanistic investigation.

• Erwan Galardon, Emilie Bourlès, Isabelle Artaud, Jean Claude Daran, Pascal Roussel, A. Corral Tomàs
• Inorganic chemistry
• 2007

Thiosulfinates are an emerging class of oxidized sulfur species that are frequently supposed to be involved in biochemical processes. Reaction of 12- and 10-membered ring pseudopeptidic… (More)

Transition from hydrogen atom to hydride abstraction by Mn4O4(O2PPh2)6 versus [Mn4O4(O2PPh2)6]+: O-H bond dissociation energies and the formation of Mn4O3(OH)(O2PPh2)6.

• Thomas W G Carrell, Emilie Bourlès, Matthew Lin, Gary Dismukes
• Inorganic chemistry
• 2003

Synthesis, characterization, and reactions of the novel manganese-oxo cubane complex [Mn(4)O(4)(O(2)PPh(2))(6)](ClO(4)), 1+ (ClO(4)(-)), are described. Cation 1+ is composed of the [Mn(4)O(4)](7+)… (More)

Kinetics of proton-coupled electron-transfer reactions

• Marcelino Maneiro, Wolfgang F. Ruettinger, Emilie Bourlès, George L. McLendon, Gary Dismukes
• 2003

The kinetics of proton-coupled electron-transfer (pcet) reactions are reported for Mn4O4(O2PPh2)6, 1, and [Mn4O4(O2PPh2)6] , 1 , with phenothiazine (pzH). Both pcet reactions form 1H, by H transfer… (More)

Cyclic peptides bearing a side-chain tail: a tool to model the structure and reactivity of protein zinc sites.

• Olivier Sénèque, Emilie Bourlès, Vincent Lebrun, Estelle Bonnet, Pascal Dumy, J. F. Latour
• Angewandte Chemie
• 2008

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