Eléna Ishow

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We have designed, synthesized, and investigated a self-assembling supramolecular system which mimics, at a molecular level, the function performed by a macroscopic electrical extension cable. The system is made up of three components, 12+, 2-H3+, and 3. Component 12+ consists of two moieties: a [Ru(bpy)3]2+ unit, which plays the role of an electron donor(More)
A series of emitting push-pull triarylamine derivatives, models of their widely used homologues in photonics and organic electronics, was investigated by steady-state and time-resolved spectroscopy. Their structural originality stems from the sole change of the electron-withdrawing substituent X (-H: 1, -CN: 2, -NO2: 3, -CHC(CN)2: 4), giving rise to(More)
Concentration quenching is a major impediment to efficient organic light-emitting devices. We herein report on Organic Light-Emitting Diodes (OLEDs) based on a fluorescent amorphous red-emitting starbust triarylamine molecule (4-di(4’-tert-butylbiphenyl-4-yl)amino4’-dicyanovinylbenzene, named FVIN), exhibiting a very small sensitivity to concentration(More)
A series of dipolar triphenylaminoazo derivatives, with largely distinct charge transfer and glass transition temperatures, has been synthesized. Their photomigration capability in the solid state to form surface relief gratings (SRGs) under interferential illumination has been investigated with respect to their photochromic properties and showed a(More)
This article reports on a comprehensive study of the two-photon absorption (2PA) properties of six novel push-pull octupolar triarylamine compounds as a function of the nature of the electron-withdrawing groups. These compounds present an octupolar structure consisting of a triarylamine core bearing two 3,3'-bis(trifluoromethyl)phenyl arms and a third group(More)
Fluorescent switching systems containing photochromic molecules have attracted significant attention on account of their potential uses as optical memory media and photoswitchable devices. Most systems offering the photomodulation of luminescence involve a photochrome covalently linked to an organic or metal–organic fluorophore, wherein the luminescence is(More)