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  • E. Yeh, Sylvie Garneau, C. Walsh
  • Chemistry, Medicine
  • Proceedings of the National Academy of Sciences…
  • 2005 (First Publication: 15 March 2005)
  • The indolocarbazole antitumor agent rebeccamycin is modified by chlorine atoms on each of two indole moieties of the aglycone scaffold. These halogens are incorporated during the initial step of itsExpand
  • P. Dorrestein, E. Yeh, S. Garneau-Tsodikova, N. Kelleher, C. Walsh
  • Chemistry, Medicine
  • Proceedings of the National Academy of Sciences…
  • 2005 (First Publication: 27 September 2005)
  • The antifungal natural product pyoluteorin contains a 4,5-dichloropyrrole moiety. The timing of dichlorination in the heteroaromatic ring is now shown to occur after proline is tethered by thioesterExpand