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A Strategy for the Convergent and Stereoselective Assembly of Polycyclic Molecules.
The stereoselective oxidative coupling of cyclic ketones via silyl bis-enol ethers followed by ring-closing metathesis is shown to be a general and powerful reaction sequence for the preparation ofExpand
Diene Synthesis by the Reductive Transposition of 1,2-Allenols
Monoalkyl diazene species are versatile intermediates that have enabled many useful synthetic transformations in complex chemical environments. Herein we report the reductive transposition ofExpand
Correction to "A Strategy for the Convergent and Stereoselective Assembly of Polycyclic Molecules".
TLDR
It has come to the authors' attention that there is an error in the compound concentrations employed for the cytotoxicity assays, and the correct IC50 values for bisepoxide 32 are 200μM against MDA-MB-231-LM24 cells and 3100 μM against non-tumorigenic MCF10A cells. Expand