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Experimental and theoretical charge density of hydrated cupric acetate
Abstract The charge density of the hydrated cupric acetate Cu2(μ-OOCCH3)4·2H2O has been studied experimentally at 100 K and by DFT calculations on the isolated molecule using the Quantum Theory ofExpand
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The vibrational spectra of the cyanide ligand revisited: the ν(CN) infrared and Raman spectroscopy of Prussian blue and its analogues
A careful analysis of the Raman spectra of the M′x[M(CN)6]y Prussian blue species has enabled a general model for the interpretation of the ν(CN) vibrational spectra. The spectral patterns areExpand
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Vibrational–Structural Combined Study into Luminescent Mixed Copper(I)/Copper(II) Cyanide Coordination Polymers
Herein, we report the characterization of a series of CuCN-based coordination polymers that display different crystal packing and electronic properties, namely, [Na2Cu(CN)3·3H2O]n (1),Expand
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Iron−Rhodium and Iron−Iridium Mixed-Metal Nitrido−Carbonyl Clusters. Synthesis, Characterization, Redox Properties, and Solid-State Structure of the Octahedral Clusters [Fe5RhN(CO)15]2-,
The cluster [Fe(5)RhN(CO)(15)](2)(-) was synthesized in 40% yield from [Fe(4)N(CO)(12)](-) and [Rh(CO)(4)](-) in refluxing tetrahydrofuran, whereas the analogous anion [Fe(5)IrN(CO)(15)](2)(-) wasExpand
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The vibrational spectra of the cyanide ligand revisited. Bridging cyanides.
The nu(CN) vibrational spectra of cyanide groups bridging two metal atoms present a confused picture. Factors relevant to the interpretation of the available data are reviewed. Some mechanisms forExpand
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Vibrational study of some layered structures based on titanium and zirconium phosphates.
A Raman and infrared study was carried out on layered zirconium and titanium acid phosphates of alpha- and gamma-type, alpha-M[O(3)POH](2).H(2)O and gamma-M[PO(4)][O(2)P(OH)(2)].2H(2)O, respectively.Expand
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Identification of dyestuffs in historical textiles: Strong and weak points of a non-invasive approach
The dyers of the past exploited a number of natural dyestuffs and dyeing procedures to obtain countless beautiful colours. It is hard to disclose which dyestuff has been used to dye a historical orExpand
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A carborane-derivative "click" reaction under heterogeneous conditions for the synthesis of a promising lipophilic MRI/GdBNCT agent.
In this study, the Huisgen reaction has been used to functionalise a carborane cage with a lipophilic moiety and a 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (DOTA) ligand to obtain aExpand
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Functionalization of sol gel bioactive glasses carrying Au nanoparticles: selective Au affinity for amino and thiol ligand groups.
It is demonstrated here that bioactive glasses containing Au nanoparticles (AuNPs) can be selectively functionalized with small molecules carrying either amino or thiol groups by simply varying theExpand
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Vibrational Study of (η5-Cyclopentadienyl)metal Complexes
Raman and infrared spectral data on the vibrational modes of the M−(η5-C5H5) unit have been collected and the fundamental assignments revisited. Complexes belonging to the metallocene seriesExpand
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