Author pages are created from data sourced from our academic publisher partnerships and public sources.
Share This Author
Decamethyldizincocene, a Stable Compound of Zn(I) with a Zn-Zn Bond
Unlike mercury, which has an extensive +1 oxidation state chemistry, zinc usually adopts the +2 oxidation state. Decamethyldizincocene, Zn2(η5-C5Me5)2, an organometallic compound of Zn(I) formally… Expand
Synthesis and insertion reactions of the cyclometalated palladium-alkyl complexes Pd(CH(2)CMe(2)-o-C(6)H(4))L(2). Observation of a pentacoordinated intermediate in the insertion of SO(2).
Palladacycles of the type 2, have been synthesized by treatment of the corresponding chloroalkylcomplexes Pd(CH(2)CMe(2)C(6)H(5))ClL(2) (L(2) = (PMe(3))(2), 2a, or 1,5-cyclooctadiene (cod), 2b) with… Expand
Bis(ethylene) complexes of molybdenum and tungsten and their reactivity toward carbon dioxide. New examples of acrylate formation by coupling of ethylene and carbon dioxide
Formation of carboxylate complexes from the reactions of carbon dioxide with ethylene complexes of molybdenum and tungsten. X-ray and neutron diffraction studies
Dihydrogen-catalyzed reversible carbon-hydrogen and nitrogen-hydrogen bond formation in organometallic iridium complexes.
Synthesis and reactivity studies on alkyl-aryloxo complexes of nickel containing chelating diphosphines: cyclometallation and carbonylation reactions
Nickel alkyl–aryloxo complexes of composition Ni(R)(OC6H32,6-Me2)(PP) (R= CH2SiMe3 ,C H 3 ,C H 2CMe2Ph; PPPPr2 (CH2)nPPr2 , n=2 (dippe) or 3 (dippp)) have been synthesized. While the… Expand
Reaction of cis-[Mo(N2)2(PMe3)4] with carbon dioxide. Synthesis and characterization of products of disproportionation and the x-ray structure of a tetrametallic mixed-valence Mo(II)-Mo(V) carbonate…
Zinc-zinc bonded zincocene structures. Synthesis and characterization of Zn2(eta5-C5Me5)2 and Zn2(eta5-C5Me4Et)2.
- A. Grirrane, I. Resa, +7 authors R. Andersen
- Chemistry, Medicine
- Journal of the American Chemical Society
- 24 January 2007
While, in general, decamethylzincocene, Zn(C5Me5)2, and other zincocenes, Zn(C5Me4R)2 (R = H, But, SiMe3), react with dialkyl and diaryl derivatives, ZnR'2, to give the half-sandwich compounds… Expand
Theoretical and synthetic studies on [Zn2(eta5-C5Me5)2]: analysis of the Zn-Zn bonding interaction.
C-H bond activation reactions of ethers that generate iridium carbenes.
- S. Conejero, M. Paneque, M. L. Poveda, L. Santos, E. Carmona
- Chemistry, Medicine
- Accounts of chemical research
- 29 January 2010
Two important objectives in organometallic chemistry are to understand C-H bond activation reactions mediated by transition metal compounds and then to develop efficient ways of functionalizing the… Expand