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Self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states.
TLDR
Carboxylate-bearing d-transition metal bipyridyls form ternary complexes with seven-coordinate Lanthanide centers that exhibit lanthanide-centered emissions sensitized by the MLCT states of the d-block components.
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Incorporation of basic side chains into cryptolepine scaffold: structure-antimalarial activity relationships and mechanistic studies.
TLDR
These novel cryptolepine analogues with substantially improved antiplasmodial activity and selectivity index provide a promising starting point for development of potent and highly selective agents against drug-resistant malaria parasites.
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Non-symmetrical furan-amidines as novel leads for the treatment of cancer and malaria.
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Target-assembled tandem oligonucleotide systems based on exciplexes for detecting DNA mismatches and single nucleotide polymorphisms.
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NMR detects molecular interactions of graphene with aromatic and aliphatic hydrocarbons in water
Polyaromatic carbon is widely held to be strongly diamagnetic and hydrophobic, with textbook van der Waals and ‘π-stacked’ binding of hydrocarbons, which disrupt their self-assembled supramolecular…
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Strong, Specific, Reversible Binding Ligands for Transfer RNA: Comparison by Fluoresence and NMR Spectroscopies with Distamycin Binding for a New Structural Class of Ligand
Abstract Binding data are presented for the interaction with brewer's yeast tRNAPhc of a new structural family of ligands, symmetrical bis-benzimidazoles. In addition specific perturbations in…
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Experimental precedent for the need to involve the primary hydration layer of DNA in lead drug design.
The increase in fluorescence on binding of m-phenyl substituted hydroxy derivatives of Hoechst 33258 with poly-[d(A-T)], d(CGCGAATTCGCG) 2 , and with the corresponding T 4 -looped 28-mer AATT hairpin…
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DNA-mounted self-assembly: new approaches for genomic analysis and SNP detection.
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A de novo self-assembling peptide hydrogel biosensor with covalently immobilised DNA-recognising motifs.
We report here the first experimental evidence of a self-assembling three-dimensional (3D) peptide hydrogel, with recognition motifs immobilized on the surface of fibres capable of sequence-specific…
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Tryptophan as a molecular shovel in the glycosyl transfer activity of Trypanosoma cruzi trans-sialidase.
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