E. Mielczarski

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We studied the adsorption of bovine serum albumin (BSA) from phosphate-buffered saline (pH 7.4) to hydrophilic and hydrophobic surfaces. Attenuated total reflection Fourier transform infrared spectroscopy, supported by spectral simulation, allowed us to determine with high precision the amount of BSA adsorbed (surface coverage) and its structural(More)
Herein, we report our analysis of the surface modification of polystyrene (PS) when treated under ambient conditions with a common biological buffer such as phosphate buffered saline (PBS) or aqueous solutions of the ionic constituents of PBS. Attenuated total reflection Fourier transform infrared spectroscopy was used for the analysis because the resultant(More)
Hybrid organic-inorganic films consisted of molecular layers of a Keggin-structure polyoxometalate (POM: 12-tungstophosphoric acid, H(3)PW(12)O(40)) and 1,12-diaminododecane (DD) on 3-aminopropyl triethoxysilane (APTES)-modified silicon surface, fabricated via the layer-by-layer (LBL) self-assembly method are evaluated as molecular materials for electronic(More)
The efficiency of a pre-absorbed bovine serum albumin (BSA) layer in blocking the non-specific adsorption of different proteins on hydrophobic and hydrophilic surfaces was evaluated qualitatively and quantitatively using infrared reflection spectroscopy supported by spectral simulations. A BSA layer with a surface coverage of 35% of a close-packed monolayer(More)
AbSTrACT The main aim of TASNANO project is to focus on the development of a web-based system that allows cooperative work between partners. Even if some commercial tools become available, the specificities of nanotechnology applications suggest implementing an ad-hoc tool. This approach permits to update information every moment, so that not only the(More)
An innovative way to fix preformed nanocrystalline TiO(2) on low-density polyethylene film (LDPE-TiO(2)) is presented. The LDPE-TiO(2) film was able to mediate the complete photodiscoloration of Orange II using about seven times less catalyst than a TiO(2) suspension and proceeded with a photonic efficiency of approximately 0.02. The catalyst shows(More)
Two fluorinated/siloxane copolymers, O5/19 and D5/3, carrying 6 and 8 CF(2) groups in the fluoroalkyl tail, respectively, were used as the surface-active components of cured poly(dimethylsiloxane) (PDMS) blends at different loadings (0.3-5.0 wt % with respect to PDMS). The surface chemical composition was determined by angle-resolved X-ray photoelectron(More)
Although the decomposition of water pollutants in the presence of metallic iron is known, the reaction pathways and mechanisms of the decomposition of azo-dyes have been meagerly investigated. The interface phenomena taking place during orange I decomposition have been investigated with the use of infrared external reflection spectroscopy, X-ray(More)
Although oxidation/passivation of iron in basic solution has been extensively investigated, there is very little information on iron corrosion in weak acidic solutions. In this work, iron surface composition and structure, produced in aerobic aqueous solutions ranging from pH 2 to 5, were determined in detail by the use of infrared external reflection(More)
A new type of Nafion/Fe structured membrane ensuring faster kinetics, higher efficiency, and mechanical properties has been prepared and will be compared in its performance with the Fe-exchanged commercial Dupont 117 Nafion/Fe membrane during the abatement of model organic compounds. During the casting of the laboratory Nafion sample, the iron ions were(More)